vSphere 6:
In the Web Client browse to your host and select Manage - Storage - Storage Devices.
Now select the disk you want to mark as SSD and click the F icon.
Now we can see in the Web Client that the disk is marked as Flash.
vSphere 5:
Our LUN vmfs-coexist is currently tagged as a normal HDD
SSH into your ESXi host and issue esxcli storage nmp device list to note your hardware device id.
Now we need to create a new claim rule to mark the disk as Flash and the reclaim the device.
And that's it we can see the disk now as Flash